JOURNAL ARTICLE

In situ Generated Iridium Nanoparticles as Hydride Donors in Photoredox‐Catalyzed Hydrogen Isotope Exchange Reactions with Deuterium and Tritium Gas.

  • Published In: Angewandte Chemie International Edition, 2023, v. 62, n. 36. P. 1 1 of 3

  • Database: Academic Search Ultimate 2 of 3

  • Authored By: Kramp, Henrik; Weck, Remo; Sandvoss, Martin; Sib, Anna; Mencia, Gabriel; Fazzini, Pier‐Francesco; Chaudret, Bruno; Derdau, Volker 3 of 3

Abstract

We have studied the photoredox‐catalyzed hydrogen isotope exchange (HIE) reaction with deuterium or tritium gas as isotope sources and in situ formed transition metal nanoparticles as hydrogen atom transfer pre‐catalysts. By this means we have found synergistic reactivities applying two different HIE mechanisms, namely photoredox‐catalyzed and CH‐functionalization HIE leading to the synthesis of highly deuterated complex molecules. Finally, we adopted these findings successfully to tritium chemistry. [ABSTRACT FROM AUTHOR]

Additional Information

  • Source:Angewandte Chemie International Edition. 2023/09, Vol. 62, Issue 36, p1
  • Document Type:Article
  • Subject Area:Chemistry
  • Publication Date:2023
  • ISSN:1433-7851
  • DOI:10.1002/anie.202308983
  • Accession Number:171105810
  • Copyright Statement:Copyright of Angewandte Chemie International Edition is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Looking to go deeper into this topic? Look for more articles on EBSCOhost.