Mechanically Adaptive Materials Based on Dynamic Chemical Bonds.

Adaptiveness is an important feature for biological creatures to survive and interact with variable environments. Mechanically adaptive polymers (MAPs), which have been developed recently inspired by this adaptive nature, can regulate their mechanical properties in response to external stimuli or environmental changes. Specifically, MAPs based on dynamic chemical bonds have been synthesized and reported as an emerging material because of the intrinsic self‐adaptability, outstanding mechanical properties and durable applications. This review primarily focuses on the recent advancements in the fabrication of MAPs through the utilization of dynamic covalent bonds and non‐covalent bonds. A comprehensive summary of the methodologies and mechanisms employed to attain high energy dissipation in MAPs is provided. Subsequently, the review offers incisive analyses of the intrinsic functionalities of MAPs, such as high impact‐stiffening, damping, and buffering capabilities. Finally, the developmental achievements within this domain are recapitulated, the potential challenges, and future research perspectives in MAPs are deliberated. [ABSTRACT FROM AUTHOR]