Comprehensive Insight Into Electronic Modulation of Rare‐Earth Elements for Enhancing Electrocatalytic Performance of Atomically Dispersed Materials.

Atomically dispersed materials have been a thriving research field due to their maximum atomic utilization and remarkable performance in energy conversion and storage systems. Owing to the large atomic radius, strong oxophilicity, and unique electronic properties, rare‐earth (RE) elements have been widely investigated as oxide carriers and promoters in atomically dispersed materials to manipulate and regulate the electronic structure of active species. Single‐atom state with an adjustable coordination environment on the N‐doped carbon endows RE metals with special electronic states and outstanding catalytic performances. A thorough comprehension of the electronic modulation mechanism of RE elements paves the way for the construction of advanced RE‐based electrocatalysts with high activity, stability, and selectivity. This review provides a widespread insight into the roles of RE elements in modulating the electronic properties of atomically dispersed materials combined with the structure–performance relationship in electrocatalysis processes. The characteristic physical and chemical properties of RE elements are highlighted, and the synthetic strategy of RE‐based atomically dispersed materials is discussed. Finally, a summary and perspectives for rational design and development of highly efficient RE‐based catalysts are proposed. This review aims to provide a guideline for promoting the rational and effective utilization of RE elements in advanced functional materials. [ABSTRACT FROM AUTHOR]