Solubility behavior and thermodynamic modeling of sodium monosulfoaluminate ("U‐phase") in cementitious systems.

The "U‐phase," a sodium‐containing (alumino‐ferrite‐monosubstituent) AFm phase, has been observed to form in sodium‐enriched highly alkaline cementitious systems, for example, of relevance to nuclear waste, and saline industrial brine management. But, minimal information is available of the U‐phase's (e.g., solubility or thermodynamic properties) due to its limited stability and its tendency to transform into ettringite or monosulfoaluminate. Herein, the U‐phase was systematically synthesized at four temperatures (5, 15, 25, and 50°C) and fully characterized in terms of its thermochemical properties. The average composition of the synthesized U‐phase (4CaO·Al2O3·1.85SO3·0.85Na2O·12H2O) deviates slightly from typical disclosures in the literature. The solubility product of the U‐phase formation was measured from conditions of oversaturation. The measured thermodynamic data accurately predicted experimental observations of U‐phase formation in cementitious environments. In general, it was noted that the U‐phase forms and persists (i.e., remains stable) at pH > 13.7 and [Na+] concentrations superior to 1 mol/L. [ABSTRACT FROM AUTHOR]