JOURNAL ARTICLE

Cu‐Catalyzed Enantioselective Reductive Coupling of 1,3‐Dienes and Carboxylic Acid Anhydrides.

  • Published In: Asian Journal of Organic Chemistry, 2023, v. 12, n. 11. P. 1 1 of 3

  • Database: Applied Science & Technology Source Ultimate 2 of 3

  • Authored By: Lu, Wenxin; Chong, Qinglei; Meng, Fanke 3 of 3

Abstract

Catalytic chemo‐, regio‐ and enantioselective construction of allyl‐Cu complexes generated from a Cu−H addition to trans‐1,3‐dienes followed by in situ addition to anhydrides to construct homoallylic alcohols is presented. This method is distinguished by a characteristic pathway to generate enantiomerically enriched allyl‐Cu species, which react with a wide range of anhydrides in high chemo‐, regio‐ and stereoselectivity. Functionalization of homoallylic alcohol products provides useful building blocks which are otherwise difficult to obtain. [ABSTRACT FROM AUTHOR]

Additional Information

  • Source:Asian Journal of Organic Chemistry. 2023/11, Vol. 12, Issue 11, p1
  • Document Type:Article
  • Subject Area:Chemistry
  • Publication Date:2023
  • ISSN:21935807
  • DOI:10.1002/ajoc.202300436
  • Accession Number:173823906
  • Copyright Statement:Copyright of Asian Journal of Organic Chemistry is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Looking to go deeper into this topic? Look for more articles on EBSCOhost.