JOURNAL ARTICLE

Iron‐Catalyzed Cross‐Coupling Reactions of Alkyl Grignard Reagents with Alkenyl Carbonate.

  • Published In: Advanced Synthesis & Catalysis, 2024, v. 366, n. 24. P. 5026 1 of 3

  • Database: Academic Search Ultimate 2 of 3

  • Authored By: Qin, Hongjian; Yang, Xingbang; Mintah Bonku, Emmanuel; Zhu, Fuqiang; Abduahadi, Safomuddin; Yang, Peng; Shen, Jingshan; Akber Aisa, Haji 3 of 3

Abstract

Herein, we report the alkylation of alkenyl carbonates using alkyl Grignard reagents and iron catalysis to generate C(sp2)−C(sp3) bonds and provide synthetically useful yields over a range of substrates. The transformation allows the alkylation of a wide range of substrates, including aromatic rings, alkanes, cycloalkanes, heterocycles. This reaction has introduced a new family of electrophiles to the iron‐catalyzed cross‐coupling reactions. [ABSTRACT FROM AUTHOR]

Additional Information

  • Source:Advanced Synthesis & Catalysis. 2024/12, Vol. 366, Issue 24, p5026
  • Document Type:Article
  • Subject Area:Geology
  • Publication Date:2024
  • ISSN:1615-4150
  • DOI:10.1002/adsc.202400979
  • Accession Number:181948362
  • Copyright Statement:Copyright of Advanced Synthesis & Catalysis is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Looking to go deeper into this topic? Look for more articles on EBSCOhost.